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bicyclo[2.2.1]heptane-2,3-dione,1,7,7-trimethyl-

Camphorequinone

CAS: 10373-78-1

Molecular Formula: C10H14O2

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bicyclo[2.2.1]heptane-2,3-dione,1,7,7-trimethyl- - Names and Identifiers

Name Camphorequinone
Synonyms camphoquinone
Camphorquinone
Camphorequinone
(±)-camphandione
dl-Camphorquinone
dl-Camphor quinone
Mixed camphorquinone
dl-Bornane-2,3-dione
Synthesis camphorquinone
DL-CAMPHORQUINONE FOR SYNTHESIS
1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione
4,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione
bicyclo[2.2.1]heptane-2,3-dione,1,7,7-trimethyl-
Bicyclo(2.2.1)heptane-2,3-dione, 1,7,7-trimethyl-
Bicyclo[2.2.1]heptane-2,3-dione, 1,7,7-trimethyl-
3-dione,1,7,7-trimethyl-,(+-)-Bicyclo[2.2.1]heptane-2
(1S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptane-2,3-dione
CAS 10373-78-1
EINECS 233-814-1
InChI InChI=1/C10H14O2/c1-9(2)6-4-5-10(9,3)8(12)7(6)11/h6H,4-5H2,1-3H3/t6-,10-/m1/s1

bicyclo[2.2.1]heptane-2,3-dione,1,7,7-trimethyl- - Physico-chemical Properties

Molecular FormulaC10H14O2
Molar Mass166.22
Density0.9817 (rough estimate)
Melting Point197-203 °C (lit.)
Boling Point234.44°C (rough estimate)
Specific Rotation(α)-5～+5°(20℃/D)(c=2, CHCl3)
Flash Point83°C
Solubility Soluble in ethanol, ethyl ether and benzene.
Vapor Presure0.0817mmHg at 25°C
AppearanceYellow to orange powder
ColorYellow
BRN1909463
Storage ConditionStore below +30°C.
Refractive Index1.4859 (estimate)
MDLMFCD00064160

bicyclo[2.2.1]heptane-2,3-dione,1,7,7-trimethyl- - Risk and Safety

Risk CodesR20/21/22 - Harmful by inhalation, in contact with skin and if swallowed.
R36/37/38 - Irritating to eyes, respiratory system and skin.
Safety DescriptionS22 - Do not breathe dust.
S24/25 - Avoid contact with skin and eyes.
S36 - Wear suitable protective clothing.
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
WGK Germany3
TSCAYes
HS Code2914 29 00

bicyclo[2.2.1]heptane-2,3-dione,1,7,7-trimethyl- - Reference Information

EPA chemical information Information provided by: ofmpub.epa.gov (external link)
introduction camphor quinone is a monoterpenoid diketone compound with physiological activity and photosensitive activity. it is also an important chiral synthesis intermediate and is widely used in biology, medicine, electronics, chemical industry and other related fields. For example, camphor quinone can be used as a probe reagent to study the characteristics of combinatorial enzymes.
application as a high-efficiency and low-toxicity photosensitizer in the field of medicine, it is used to manufacture propylene lenses, dental fillers, enamel repair agents, dental adhesives, surgical molded products, medical plasters, etc.; in industry, camphorquinone is used to manufacture printed circuit boards in the field of electronics industry, the sealing insulation of photoelectric instruments, developing materials, recording media in holography and printing, copying, fax and other equipment, photopolymerization catalysts, etc., can also be used to manufacture photodegradable ethylene polymers. This is obviously also very problematic for alleviating environmental pollution. In addition, camphor paste is an important chiral intermediate and is widely used as a chiral precursor in asymmetric synthesis.
Preparation In 1934, Evans et al. discovered that camphor quinone can be obtained by directly oxidizing camphor with selenium dioxide in acetic acid. Typical conditions for the reaction are heating for 3-4h at 140-150°C. After the reaction is over, it is extracted with acetic acid, and after the extract is neutralized with concentrated lye, camphor wakes out because it is insoluble in water. Then use sublimation method or recrystallization method to purify. This method has simple steps and high yield, reaching about 90%, so it is still widely used by people. However, the selenium dioxide used in the method is a highly toxic compound, and there are residues of selenium substances in the product, which will limit the application of camphor quinone in medicine.
Last Update：2024-04-09 21:11:58
bicyclo[2.2.1]heptane-2,3-dione,1,7,7-trimethyl-
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Hefei TNJ Chemical Industry Co.,Ltd.
Product Name: Camphorequinone Request for quotation
CAS: 10373-78-1
Tel: 0086-551-65418684
Email: sales@tnjchem.com
　　　　 info@tnjchem.com
Mobile: 0086 189 4982 3763
QQ: 2881500840 Click to send a QQ message
Wechat: 0086 189 4982 3763
WhatsApp: 0086 189 4982 3763
Product List: View Catalog
Shanghai Yuanye Bio-Technology Co., Ltd.
Product Name: (±)-Camphorquinone Visit Supplier Webpage Request for quotation
CAS: 10373-78-1
Tel: 18301782025
Email: 3008007409@qq.com
Mobile: 18021002903
QQ: 3008007409 Click to send a QQ message
Wechat: 18301782025
Hubei hong xin yu chemical co., LTD
Product Name: Camphorequinone Request for quotation
CAS: 10373-78-1
Tel: 027-65385071
Email: 2056564811@qq.com
Mobile: 17771822910
QQ: 1603635527 Click to send a QQ messageSend QQ message
View History
bicyclo[2.2.1]heptane-2,3-dione,1,7,7-trimethyl-
136675-26-8
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